The application of aromatic probe molecules in the surface acid properties study of modified alumina catalysts by EPR spectroscopy

  • V.L . Yurpalov Institute of hydrocarbon processing problems SB RAS
  • V.A. Drozdov Institute of hydrocarbon processing problems SB RAS
  • A.A. Nepomnyashchy Institute of hydrocarbon processing problems SB RAS
  • E.A. Buluchevskiy Institute of hydrocarbon processing problems SB RAS
Keywords: catalyst, surface acidity, Bronsted Acid Sites, modified alumina, probe EPR spectroscopy

Abstract

Current paper systematizes the work devoted to the application of the aromatic spin probe EPR spectroscopy for the study of heterogeneous alumina catalysts, as well as supplemented by new researches carried out in IHP SB RAS. The advances of the method and the mechanism of probe molecules interaction with active surface sites and their nature are considered. There are noted some contradictions in views on mechanisms, nevertheless the modern point of view tends to participate BAS in the ionization of aromatic probe molecules.

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Published
2019-02-01
How to Cite
Yurpalov, V. ., Drozdov, V., Nepomnyashchy, A., & Buluchevskiy, E. (2019). The application of aromatic probe molecules in the surface acid properties study of modified alumina catalysts by EPR spectroscopy. Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal), 62(1-2), 124-130. https://doi.org/10.6060/rcj.2018621-2.10

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