THE INFLUENCE OF MECHANICAL ACTIVATION ON THE PROPERTIES SUPPORTS AND CATALYSTS OF OIL REFINING
Abstract
The analysis of scientific publications and patents devoted to mechanochemical synthesis of inorganic supports and catalysts of oil processing processes: cracking, reforming, hydrotreating and hydrocracking is carried out. It s shown that the introduction of mechanical activation into the technological process of synthesis of inorganic supports and catalysts, as a rule, leads to an increase in catalytic activity and selectivity. Features of mechanochemical synthesis of complex nickel-molybdenum oxides, which are precursors of sulfide nickel-molybdenum hydrotreating catalysts, were considered. It is shown that under conditions of mechanical activation, it is possible to obtain a nickel-molybdenum highly active and thermostable β-NiMoO4, in which Mo is in a tetrahedral conformation. The technology of obtaining highly dispersed carbide-containing catalysts developed using the IHCP SB RAS using the method of mechanical activation is described. The texture and morphology of synthesized highly disperse massive carbide-containing catalysts are considered. It is shown that the size of active particles is 2–5 nm. Model catalytic tests have been carried out and it has been established that carbide-containing highly disperse catalysts exhibit high catalytic activity in the model hydrodesulphurization reaction of dibenzothiophene.
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